Speaker
Mr
Farhad Izadi
(1. Institute for Ion Physics and Applied Physics, University of Innsbruck)
Description
Electron capture by molecules leads to the formation of transient negative ions, which may dissociate through dissociative electron attachment (DEA). DEA to the 1-bromoacetyl-3,3-dinitroazetidin (RRx-001) molecule in the gas phase has been studied utilizing a crossed electron-molecular beam setup combined with a quadrupole mass spectrometer. RRx-001 has been proposed as a radiosensitizer. We observed 11 fragment anions, which indicate that low-energy electrons with kinetic energies ranging from 0 to 14 eV strongly decompose the molecule. The results indicate efficient formation of NO2– and Br– upon DEA to RRx-001.
Primary authors
Mr
Farhad Izadi
(1. Institute for Ion Physics and Applied Physics, University of Innsbruck)
Mr
Eugene Arthur-Baidoo
(Institute for Ion Physics and Applied Physics, University of Innsbruck,)
Prof.
Stephan Denifl
(Institute for Ion Physics and Applied Physics, University of Innsbruck, Technikerstrasse 25, 6020 Innsbruck, Austria.)