August 30, 2021 to September 3, 2021
University of Innsbruck
Europe/Zurich timezone

【442】Core-valence attosecond transient absorption spectroscopy of polyatomic molecules

Sep 2, 2021, 2:45 PM
15m
Room E

Room E

Talk Atomic Physics and Quantum Optics Atomic Physics and Quantum Optics

Speaker

Dr Nikolay Golubev (Laboratory of Theoretical Physical Chemistry, Institut des Sciences et Ingenierie Chimiques, Ecole Polytechnique Federale de Lausanne (EPFL))

Description

Tracing ultrafast processes induced by interaction of light with matter is often very challenging. In molecular systems, the initially created electronic coherence becomes damped by nuclear rearrangement on a femtosecond timescale which makes observations of electron dynamics in molecules particularly difficult. We demonstrate that the attosecond transient absorption spectroscopy (ATAS) can be a very useful technique to trace such ultrafast processes. We report the application of ATAS to probe the oscillations of the positive charge created after ionization of the propiolic acid molecule. By taking advantage of element-specific core-to-valence transitions, we show that the resolution of ATAS makes it possible to trace the dynamics of electron density with atomic resolution.

Primary authors

Prof. Alexander Kuleff (Theoretische Chemie, Universitat Heidelberg) Prof. Jiří Vaníček (Laboratory of Theoretical Physical Chemistry, Institut des Sciences et Ingenierie Chimiques, Ecole Polytechnique Federale de Lausanne (EPFL)) Dr Nikolay Golubev (Laboratory of Theoretical Physical Chemistry, Institut des Sciences et Ingenierie Chimiques, Ecole Polytechnique Federale de Lausanne (EPFL))

Presentation materials

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