Speaker
Prof.
Sergey Kulyukhin
(Institute of Physical Chemistry and Electrochemistry RAS)
Description
The localization of volatile radioactive iodine compounds by various sorbents from vapor-gas media is a vital issue for environmental protection during both irradiated nuclear fuel reprocessing and accidents at nuclear power enterprises, including nuclear power plants (NPPs).
The work studies the thermal decomposition of methyl iodide CH3131I, a volatile radioactive iodine organic compound, in a gas flow in the presence of various modifications of "Fizkhmin"TM granulated materials based on silica gel impregnated with d-elements.
Test facility concluded the following basic parts: rotameters (1); a CH3131I generator (2); scrubber with water (3); the heating furnace of mine type (4); composite materials under study (5); the thermocouple (6); a column with SiO2-Cuo (7); scrubber with 0.05 M Na2SO3 solution (8); the heating furnace of tubular type (9); columns with SiO2-AgNO3 (10).
The study found that in the absence of "Fizkhmin"TM material, the degree of the decomposition of CH3131I (10 mg) in air (flow rate 4.5–5.5 cm/s and time of the air flow presence in the heating zone 1.0 – 1.5 s) was equal to (7-10)% at (540 10)оС, ~(70-75)% at (640 10)оС, and ~(97-99)% at (770 15)оС.
In the presence of silica gel granules measuring 1.0-3.0 mm, the degree of the decomposition of CH3131I (10 mg) in air (linear flow rate 4.8–5.2 cm/s and time of the air flow presence in the heating zone 1.0–1.1 s) was equal to (2-3)% at (240 10)оС, ~(10-15)% at (340 10)оС, ~(75-80)% at (440 10)оС, and ~(97-99)% at ~(540 10)оС. Silica gel granules allow decreasing the CH3131I thermal decomposition temperature in an air flow by ~200оС.
In the presence of "Fizkhmin"TM granulated materials impregnated with Ni compounds or Ni-Cu mixture (8-10 wt.% and granule size 1.0–3.0 mm), the degree of the decomposition of CH3131I (10 mg) in air (linear flow rate 4.8–5.2 cm/s and time of the air flow presence in the heating zone 0.8–1.1 s) was equal to <0.2% at (20 3)оС, ~(0.3-1.0)% at (150 20)оС, (15-30)% at (250 10)оС, ~(85-92)% at (340 15)оС, and ~(95-99)% at (465 20)оС. "Fizkhmin"TM granules containing 8-10 wt.% Ni or its mixture with Cu, allow decreasing the CH3131I thermal decomposition temperature in an air flow by more than ~300оС.
The work studies the dependence of the CH3131I thermal decomposition degree on the concentration of a d-element in the "Fizkhmin"TM material and its storage time, as well as on the amount of CH3131I in an air flow.
Work is supported by Council about grants of the President of the Russian Federation for the state support of leading scientific schools of the Russian Federation (grant SS-6692.2010.3).
Author
Prof.
Sergey Kulyukhin
(Institute of Physical Chemistry and Electrochemistry RAS)
Co-authors
Dmitrii Levushkin
(Institute of Physical Chemistry and Electrochemistry RAS)
Igor' Rumer
(Institute of Physical Chemistry and Electrochemistry RAS)
Lubov' Mizina
(Institute of Physical Chemistry and Electrochemistry RAS)
