27–29 Nov 2016
THE GREENERY RESORT KHAO YAI
Asia/Bangkok timezone

Salicylideneaniline-Functionalized Poly(m-phenyleneethynylene)s as Fluorescent Turn-On Chemosensors for Cations

29 Nov 2016, 14:00
15m
Room2 (Greenery)

Room2

Greenery

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Oral Other related topics Heron 1

Speaker

Ms Nopparat Thavornsin (Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.)

Description

Two different series of conjugated polymer, poly(m-phenyleneethynylenes) (m-PPEs) containing different amounts of salicylideneaniline moieties (50% and 100%) have been synthesized via a post-functionalization of aniline group on m-PPEs backbone. PPEs are successfully prepared in excellent yield (90-99%) and spectroscopically characterized the structure by $^1$H, $^{13}$C NMR and FTIR exhibited signals that reasonably correlate with the desired polymer. The resulting polymers displayed weak orange emission at 560 nm and undergo remarkable turn-on bright blue fluorescent emission at 450 nm response to Fe$^{2+}$, Fe$^{3+}$, Al$^{3+}$ and Cr$^{3+}$ without any change with other cations.

Primary author

Ms Nopparat Thavornsin (Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.)

Co-author

Mr Mongkol Sukwattanasinitt (Nanotec-CU Center of Excellence on Food and Agriculture, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.)

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