Abstract. The flower-like nanostructures of SnO were successfully synthesized by a simple hydrothermal method. The structure of the flower-like samples was investigated by X-ray diffraction (XRD). The samples revealed the single phase of SnO tetragonal structure. The corresponding selected-area electron diffraction (SAED) analysis further confirmed the formation of the tetragonal structure of SnO without secondary phases. The UV-visible spectroscopy showed the absorption peaks of SnO flower-like samples in ultraviolet region centered at approximately 275 nm (4.37 eV). The estimated band gap of the samples was in the range of 3.47-3.52 eV. The magnetic properties were investigated by VSM. The flower-like sample prepared at 180C for 48 h exhibits a diamagnetic behavior, whereas the sample prepared at 180C for 24 h is ferromagnetic having the saturation magnetization of 0.574 memu/g at 15 kOe.