Speaker
Description
With regard to the development of approaches to realize “Designer Solids” by programmed assembly of building units taken form libraries, recently metal-organic frameworks (MOFs) have attracted a huge interest. Here, we will focus on MOF-based electrochemical [1,2], photoelectrochemical [3] and photovoltaic devices [4,5]. Internal interfaces in MOF heterostructures are also of interest with regard to photon-upconversion [6] and can be used for the crosslinking of sandwiched, reactive monomers [7]. Since the fabrication of reliable and reproducible contacts to MOF-materials represent a major challenge, we have developed a layer-by-layer (lbl) deposition method to produce well-defined, highly oriented and monolithic MOF thin films on a number of different substrates.
[1] A. Dragässer, O. Shekhah, O. Zybaylo, C. Shen, M. Buck, Ch. Wöll, D. Schlettwein Chem. Comm., 48, 663 (2012)
[2] J. Liu, M. Paradinas, L. Heinke, M. Buck, C. Ocal, V. Mugnaini, Ch. Wöll Chem.Electro.Chem., 3, 713 (2016)
[3] Lu Ye, J. Liu, Y. Gao, Ch. Gong, M. Addicoat, Th. Heine, Ch. Wöll, L. Sun
J. Mater. Chem. A, 4, 15320, (2016)
[4] J. Liu, W. Zhou, J. Liu, I. Howard, G. Kilibarda, S. Schlabach, D. Coupry, M. Addicoat, S. Yoneda, Y. Tsutsui, T. Sakurai, S. Seki, Zh. Wang, P. Lindemann, E. Redel, Th. Heine, Ch. Wöll, Angew. Chemie Intl. Ed., 54, 7441 (2015)
[5] J. Liu, W. Zhou, J. Liu, Y. Fujimori, T. Higashino, H. Imahori, X. Jiang, J. Zhao, T. Sakurai, Y. Hattori, W. Matsuda, Shu Seki, S. K. Garlapati, S. Dasgupta, E. Redel, L. Sun, Ch. Wöll, Journal of Mat. Chem. A, 4, 12739 (2016)
[6] M. Oldenburg, A. Turshatov, D. Busko, S. Wollgarten, M. Adams, N. Baroni, A. Welle, E. Redel, Ch. Wöll, B. S. Richards, I. A. Howard, Adv. Mater., 28, 8477 (2016)
[7] Z. Wang, A. Blaszczyk, O.Fuhr, S.Heissler, C.Wöll, M.Mayor, Nat. Comm., 8, 14442 (2017)
[8] Jin-L. Zhuang, A. Terfort, C. Wöll, Coordination Chemistry Reviews, 307, 391, (2016)
[9] J. Liu, T. Wächter, A. Irmler, P.G. Weidler, H. Gliemann, F. Pauly, V. Mugnaini, M. Zharnikov, Ch. Wöll, ACS Applied Materials & Interfaces, 7, 9824, (2015)
