【148】 Two-dimensional Raman Correlation and THz-Raman Spectroscopic Investigation of the Brill Transition in Nylon 6,6

23 Aug 2017, 12:30
1h 30m
Poster Condensed Matter Physics (incl. NESY) Poster Session

Speaker

Prof. Maurizio Musso (University of Salzburg, Department of Chemistry and Physics of Materials)

Description

The Brill transition is a phase transition process in polyamides, that has been related with structural changes between the hydrogen bonds of the lateral functional groups (C=O) and (N-H). In this study we show the potential of Raman spectroscopy for exploring this phase transition in polyamide PA66 (nylon 6,6). Raman spectra were collected during a step by step heating and cooling process of the sample from 30°C to 240°C, allowing to grasp signatures of the Brill transition from peak parameters of specific vibrational modes, and to verify the Brill transition temperature as well as the reversibility of this phase transition.

Authors

Mr Durval Bertoldo Menezes (Federal Institute of Triângulo Mineiro, Uberlândia, Minas Gerais; University of Salzburg, Department of Chemistry and Physics of Materials) Mr Andreas Reyer (University of Salzburg, Department of Chemistry and Physics of Materials) Prof. Maurizio Musso (University of Salzburg, Department of Chemistry and Physics of Materials)

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