18–21 Apr 2024
WFAIS UJ
Europe/Zurich timezone

Cerium oxide nanoparticles – influence of synthesis method on characteristics

19 Apr 2024, 14:05
20m
WFAIS UJ

WFAIS UJ

Faculty of Physics, Astronomy and Applied Computer Science, prof. St. Łojasiewicza 11, Kraków
Talk

Speaker

Andrzej Wójtowicz

Description

Cerium oxide (ceria) has recently brought extensive interest due to its possible applications in numerous fields, e.g. drug delivery and biomedical applications, photocatalysis and environmental catalysis (air purification, water cleansing, etc.). Specific redox properties together with high specific surface area make ceria nanoparticles promising catalysts for oxidation reactions. Cerium dioxide may be synthesised from various precursors and using different methods, e.g. thermal decomposition, hard or soft template synthesis, sol-gel method, sonochemical or hydrothermal synthesis. In the research a series of ceria samples and their modifications with cobalt was synthesised using various methods. The materials were characterised with X-ray powder diffraction, transmission electron microscopy (chosen systems) and tested as catalyst in the reaction of model soot (Printex U) combustion. All samples were active in the investigated reaction, with temperature of 50% soot conversion not exceeding 400ºC in tight contact mode. The catalytic performance highly depended on morphology of ceria, as well as on differences in cobalt dispersion.

Field Chemistry
Length Short 15 min

Author

Andrzej Wójtowicz

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