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Radioisotopes of 227Ac and 227,228,229Th are basis of the radiochemical generators for production of alpha-emitters radium-223, radium-224, actinium-225 and bismuth-213. These generator radionuclides are used to produce radiopharmaceuticals and therefore their radiochemical purity has to be maintained high demands. For example, actinium-225 generator has to contain less than 1·10-3 % of each Ra and Th isotopes (standard of ORNL), radium-223 generator – less than 0.5% of thorium-227 and 0.04% of actinium-227.
Irradiated radium-226 used in the presented work is contained mixture of all abovementioned isotopes with their daughter radionuclides. In frame of the presented work methods of chromatographic extraction [1] of thorium-229 and actinium-227 from irradiated radium-226 have been developed and tested with technological reprocessing procedures [2]. Activities of 226Ra, 227Ac, 227,229Th and their daughter nuclides for chemical procedures and final batches have been measured with gamma- and alpha-spectrometry. Measured activities of 227Ac and 227,229Th were compared with values calculated by a computer code.
- E.P. Horwitz, et al. // Solv. Extr. Ion Exch. 2005. V. 23. P. 319.
- B. Zieliinska et al. // Solv. Extr. Ion Exch. 2007. V. 225. P. 339.