Radiotracer experiments, in general, have turned out as a powerful tool for the study of diffusion phenomena in solids [1]. In this contribution, diffusion experiments have been performed using the unique abundance of radiotracers delivered by ISOLDE. In this way, it has been possible to show that in CdTe the group I elements 67Cu, 111Ag, 193Au, and 24Na exhibit the phenomenon of uphill diffusion, i.e. they form a symmetric concentration-depth profile that is strongly peaked about the center of a typically a few 100 µm thick crystal. It turned out that this phenomenon is observed if the diffusion is performed under external Cd pressure at temperatures of about 800 K [2,3,4]. Meanwhile, the phenomenon of uphill diffusion is understandable to a large extent in the framework of a model described in [5,6]. It takes into account the charge state of all participating intrinsic and extrinsic defects moving under the influence of an internal electric field that is generated by the inhomogeneous distribution of the charged defects.
Surprisingly enough, the phenomenon of uphill diffusion is observable, too, and that at a distinctly lower sample temperature of about 550 K, if metal layers are evaporated onto the implanted surface. Uphill diffusion of 111Ag caused by evaporated metal layers has been observed for the metals Cu, Au, Ni, and Al, up to now, whereby quantitative differences show up depending on the respective metal.
In order to extend these studies, the diffusion of the magnetic species Co and Fe in CdTe has been performed. In case of the isotope 61Co implanted at ISOLDE, again unusual diffusion profiles are observed that do not correspond to the results predicted by the simple application of Fick’s law; but, in this case, no uphill diffusion profile did occur. Using CdTe crystals exhibiting an initial Te excess, box-shaped Co diffusion profiles were observed upon diffusion under external Cd pressure for temperatures between 800 and 900 K. In contrast, using CdTe with Cd excess, a normal Gaussian diffusion profile was formed. Also the diffusion profile of Co is affected by a metal layer. The presence of a Cu layer evaporated onto the implanted surface of the sample significantly enhances the diffusion of Co at a temperature of 700 K as compared to diffusion under external Cd pressure or vacuum. Finally, first results of the diffusion of 59Fe in CdTe will be presented.
The range of radiotracers suited for diffusion experiments is significantly enlarged by setting up an online-diffusion chamber at ISOLDE. This chamber will enable the use of isotopes having half-lives of less than 1 h and is equipped for measuring concentration profiles up to 10 µm. In this way, it should be also possible to investigate diffusion conditions for tailoring structured impurity profiles at length scales of a few µm. This type of dopant profiles is of strong interest for technical applications, e.g. in magnetic materials or in semiconductors.
[1] H. Mehrer: Diffusion in Solids, Springer Series in Solid State Science Vol. 155 (Springer, Berlin, 2007)
[2] H. Wolf, F. Wagner, Th. Wichert and ISOLDE Collaboration, Phys. Rev. Lett. 94 (2005) 125901
[3] H. Wolf, F. Wagner, T Wichert, Defect and Diffusion Forum 237-240 (2005) 491.
[4] H. Wolf, F. Wagner, J. Kronenberg, Th. Wichert, and ISOLDE collaboration, Defect and Diffusion Forum 289-292 (2009) 587.
[5] H. Wolf, F. Wagner, Th. Wichert, R. Grill and E. Belas, J. Electr. Mat. 35 (2006) 1350
[6] H. Wolf, F. Wagner, J. Kronenberg, Th. Wichert, R. Grill, E. Belas, and The ISOLDE collaboration, Diffusion Fundamentals 8 (2008) 3.1-3.8.